I'm not a Nebraska fan but I'll chime in.
Personally I think NU made a wise decision in moving to the Big Ten, I've never been to the state but I think they fit well with the culture, they may not share in the Great Lakes/Rustbelt experience like so many other Big Ten schools but I think they meld better than Penn State because at the very least they're Midwestern. I wanted NU, ND or possibly Mizzou so I'm happy with the addition and its good for them athletically and academically so hey good deal.
WVU is in a completely different position. They don't have near the history that NU has as they were in the SoCon (the App State/Furman/Wofford conference) until the late 60's and have no real titles of national note. Moving to the Big XII is odd but also wise. It's like jumping from a sinking midget submarine on to a sinking Carnival Cruise ship.
Also to hit on what TJ said we line up well with the Big XII as far as top teams go (teams with national appeal and history)
Big Ten - Nebraska, Michigan, Ohio State and Penn State
Big Twelve - Oklahoma and Texas
As far as up and comers go its not too bad either
Big Ten - Wisconsin and Michigan State (fair amount of history at State as well)
Big Twelve- Oklahoma State and Kansas State
Speaking broadly, I think we have the best conference in the country.
- Stability - We're the oldest Division One conference in the country and we've never truly lost a member. (Chicago de-emphasized athletics)
- Academics - 11 of 12 members are in the AAU. We have a unique and extremely effective cooperative relationship within the conference through the CIC. Students share in reference material, research funds and projects and enjoy reciprocity with other schools not to mention it includes some of the Nation's top institutions around, (PSU, UW, Northwestern, Michigan and Illinois are all top 50 universities, as is Chicago which is also a CIC member)
- Athletics - Few other conferences can claim the level of success across a wide range of sports that the Big Ten can. 40 National titles in football, 18 Heisman Winners the winningest program in the history of the sport and the winningest program in the past 30 or so years. Oh and three of the five largest stadiums. 18 Basketball titles and three of the winningest programs in the sport. (compare to 1SEC, 2BigXII, 3Pac12, 3ACC and 6BE) Also when the Big Ten comes together to play hockey in 2013 it will have four of the top 10 overall schools in the nation with UM, UW, MSU and U of M with 23 National Titles total. Add to all of that the fact that we actually hold our athletes to a standard and its even more impressive.
So yea, I love the Big Ten. Good move NU.