Wouldn't go that far re: Pitt. Already in the footprint, and Penn State pretty much owns Pennsylvania media markets.
Syracuse, possibly--Pitt, probably not.
And this is interesting in that it was intimated that all of the 'leftovers' from the Big XII would end up as part of the Big East (read: Baylor, ISU, KSU, et al).
Perhaps some of the Big East schools aren't down with onboarding TCU next year and Big XII refugees in future years?
Baylor and ISU have pretty much offered themselves to he Big East.
http://collegefootballtalk.nbcsports.com/2011/09/17/iowa-state-baylor-reportedly-offer-themselves-to-big-east/