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I know some of you do home brewing, anyone ever try doing vodka?
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If the hillbillies can do it, probably not too difficult.
If you want to distill alcohol but not make it consumable, then there's a way to do it legally. Look up how to get a Federal Fuel Alcohol Permit. It's much easier to get than one for human consumption.
Also, it's legal to distill non-alcoholic substances like water and oil without any permit.
PS - I did this in the 80s